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We present a refined global Furongian (late Cambrian) time scale derived through the application of Bayesian age modeling, using an integrative assemblage of conditioning likelihoods (age constraints) including U-Pb zircon maximum depositional ages in the Steptoean positive isotopic carbon excursion (SPICE) reference section in Smithfield Canyon (Utah, USA) and nearby McPherson Canyon (Idaho, USA); Re-Os geochronology from the SPICE-bearing interval of the Andrarum-3 core (Scania, Sweden); and new high-precision chemical abrasion−isotope dilution−thermal ionization mass spectrometry U-Pb zircon tuff ages from Avalonian Wales. We embed these radioisotopic ages within a novel probabilistic treatment of biozones to establish temporal constraints on rock accumulation rates in the Great Basin (USA), the duration of the SPICE event, and Laurentian trilobite biozones correlated to the global Cambrian time scale. Results reveal a beginning of 494.5 (+0.7/−0.6) Ma and an end of 487.3 ± 0.08 Ma for the Furongian Epoch, representing a reduction of the traditional late Cambrian by ∼30% and an extension of the Ordovician by nearly half a million years. Furthermore, the SPICE is confined to a duration of 2.6 (+0.9/−0.8) m.y. Our new approach to integrating faunal succession into Bayesian age modeling can help to constrain rock accumulation rates and possible hiatuses in sections with limited radioisotopic ages. Additionally, it offers a robust calibration tool for further refining the numerical calibration of the geologic time scale, for testing hypotheses about the rates of trilobite evolution and extinction, for evaluating causes of the SPICE, and for constraining paleoclimatic conditions including atmospheric O2 levels. 

Deep-time thermochronology by the zircon (U-Th)/He (ZHe) method is an emerging field of study with promise for constraining Precambrian rock thermal and exhumation histories. The Grand Canyon provides an opportunity to further explore this method because excellent geologic constraints can be integrated with multiple thermochronometers to address important questions about the spatial variability of basement erosion below the sub-Cambrian Great Unconformity composite erosional surface. In this study, we synthesize new ZHe results (n = 26) and published (n = 77) ZHe data with new K-feldspar 40Ar/39Ar data and models (n = 4) from Precambrian basement rocks of the Grand Canyon, USA. We use HeFTy and QTQt thermal history modeling to evaluate the ability of the individual ZHe and K-feldspar 40Ar/39Ar thermochronometric data sets to resolve Precambrian thermal histories and compare those results with jointly modeled data using the QTQt software. We also compare Precambrian basement thermal histories of the eastern and western Grand Canyon, where the eastern Grand Canyon has ∼4 km of Grand Canyon Supergroup strata deposited and preserved, and the western Grand Canyon, where the Supergroup was either never deposited or not preserved. In all locations, models constrained only by ZHe data have limited resolving power for the past ∼600 m.y., compared to models that combine K-feldspar 40Ar/39Ar and ZHe data, which extends the recorded history into the Mesoproterozoic. Our model results suggest that two regional basement unroofing events occurred. A ca. 1350−1250 Ma cooling event is interpreted to record basement exhumation from depths of ∼10 km, and a second cooling episode (∼200−100 °C total) records exhumation from a depth of ∼3 km to 7 km to near-surface conditions between ca. 600 Ma and 500 Ma. Easternmost Grand Canyon models suggest that the preserved maximum ∼4 km thickness of the Grand Canyon Supergroup (with burial heating at ∼100 °C) approximates the total original Mesoproterozoic and Neoproterozoic stratal thickness. Whether these Supergroup rocks were present and then eroded in the western Grand Canyon, as suggested by regional geologic studies, or were never deposited is not constrained by thermochronological data. 

The Grand Canyon provides a deeply dissected view of the aquifers of the Colorado Plateau and its public and tribal lands. Stacked sandstone and karst aquifers are vertically connected by a network of faults and breccia pipes creating a complex groundwater network. Hydrochemical variations define structurally controlled groundwater sub-basins, each with main discharging springs. North Rim (N-Rim), South Rim (S-Rim), and far-west springs have different stable isotope fingerprints, reflecting different mean recharge elevations. Variation within each region reflects proportions of fast/slow aquifer pathways. Often considered perched, the upper Coconino (C) aquifer has a similar compositional range as the regional Redwall-Muav (R-M) karst aquifer, indicating connectivity. Natural and anthropogenic tracers show that recharge can travel 2 km vertically and tens of kilometers laterally in days to months via fracture conduits to mix with older karst baseflow. Six decades of piping N-Rim water to S-Rim Village and infiltration of effluent along the Bright Angel fault have sustained S-Rim groundwaters and likely induced S-Rim microseismicity. Sustainable groundwater management and uranium mining threats require better monitoring and application of hydrotectonic concepts. ▪ Hydrotectonic concepts include distinct structural sub-basins, fault fast conduits, confined aquifers, karst aquifers, upwelling geothermal fluids, and induced seismicity. ▪ N-Rim, S-Rim, and far-west springs have different stable isotope fingerprints reflecting different mean recharge elevations and residence times. ▪ The upper C and lower R-M aquifers have overlapping stable isotope fingerprints in a given region, indicating vertical connectively between aquifers. ▪ S-Rim springs and groundwater wells are being sustained by ∼60 years of piping of N-Rim water to S-Rim, also inducing seismicity. Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 52 is May 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates. 

Abstract The Southwestern Laurentia large igneous province (SWLLIP) comprises voluminous, widespread ca 1.1 Ga magmatism in the southwestern United States and northern Mexico. The timing and tempo of SWLLIP magmatism and its relationship to other late Mesoproterozoic igneous provinces have been unclear due to difficulties in dating mafic rocks at high precision. New precise U-Pb zircon dates for comagmatic felsic segregations within mafic rocks reveal distinct magmatic episodes at ca. 1098 Ma (represented by massive sills in Death Valley, California, the Grand Canyon, and central Arizona) and ca. 1083 Ma (represented by the Cardenas Basalts in the Grand Canyon and a sill in the Dead Mountains, California). The ca. 1098 Ma magmatic pulse was short-lived, lasting 0.25−0.24+0.67 m.y., and voluminous and widespread, evidenced by the ≥100 m sills in Death Valley, the Grand Canyon, and central Arizona, consistent with decompression melting of an upwelling mantle plume. The ca. 1083 Ma magmatism may have been generated by a secondary plume pulse or post-plume lithosphere extension. The ca. 1098 Ma pulse of magmatism in southwestern Laurentia occurred ~2 m.y. prior to an anomalous renewal of voluminous melt generation in the Midcontinent Rift of central Laurentia that is recorded by the ca. 1096 Ma Duluth Complex layered mafic intrusions. Rates of lateral plume spread predicted by mantle plume lubrication theory support a model where a plume derived from the deep mantle impinged near southwestern Laurentia, then spread to thinned Midcontinent Rift lithosphere over ~2 m.y. to elevate mantle temperatures and generate melt. This geodynamic hypothesis reconciles the close temporal relationships between voluminous magmatism across Laurentia and provides an explanation for that anomalous renewal of high magmatic flux within the protracted magmatic history of the Midcontinent Rift.